Liquid-Liquid Demixing from Solutions of Polystyrene 1. A Review 2. Improved Correlation with Solvent Propertie

By Imre, Attila

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Title:	Liquid-Liquid Demixing from Solutions of Polystyrene 1. A Review 2. Improved Correlation with Solvent Propertie
Author:	Imre, Attila
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Language:	English
Subject:	Technology., Reference materials, Technology and literature
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Citation APA MLA Chicago Imre, B. A. (n.d.). Liquid-Liquid Demixing from Solutions of Polystyrene 1. A Review 2. Improved Correlation with Solvent Propertie. Retrieved from http://www.gutenberg.us/

Description
Technical Reference Publication

Excerpt
Introduction: This study of the neutral oxygen fluorides is the first of four critical reviews on the thermodynamic and spectroscopic properties of the halogen oxides. An earlier partial study on...

Table of Contents
Contents 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . .6.3 8 1.1. Comments on Polymer Solubility . . . . . .6 38 1.2. PolymerfSolvent Phase Diagrams. . . . . . .6 38 2 . Literature Surveyed . . . . . . . . . . . . . . . . . . . . .6 40 3 . The Fitting of Polymer/Solvent Dernixing Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 41 3.1. Phase Behavior in (T, P,X ) Space . . . . . .6 41 3.2. Least-Squares Representation in the ( Tc, X ) Projection . . . . . . . . . . . . . . . . . .6.4 2 4 . Solvent Groups: Remarks . . . . . . . . . . . . . . . . . 644 4.1. Acetates . . . . . . . . . . . . . . . . . . . . . . . . . . . 644 4.2. Alcohols . . . . . . . . . . . . . . . . . . . . . . . . . . . 645 4.3. Alkanes and Some Derivatives . . . . . . . . . 645 4.4. Alkenes . . . . . . . . . . . . . . . . . . . . . . . . . . .6 45 4.5. Benzene and its Derivatives . . . . . . . . . .6.4 5 4.6. Esters (other than formates and acetates) . . . . . . . . . . . . . . . . . . . . . .6.4 5 4.7. Ethers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 645 4.8. Formates . . . . . . . . . . . . . . . . . . . . . . . . . . 645 4.9. Heterocyclics . . . . . . . . . . . . . . . . . . . . . .6.4 5 4.10. Ketones . . . . . . . . . . . . . . . . . . . . . . . . .6 45 4.1 1 . Terpenes. . . . . . . . . . . . . . . . . . . . . . . .6.5 2 4.12. Other Compounds . . . . . . . . . . . . . . . . . 653 5 . Solubility and Solvent Quality . . . . . . . . . . . . . 653 5.1. Correlations . . . . . . . . . . . . . . . . . . . . . . . . 653 5.2. Delnixing from Two Componcllt Solvents . . . . . . . . . . . . . . . . . . . . . . . . . . . 659 6 . Summary and Conclusions . . . . . . . . . . . . . . . .6 59 7 . Acknowledgements . . . . . . . . . . . . . . . . . . . . .6.6 0 8. References . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6 60 'Permanent address: Institute for Atomic Energy Research . POB 49 . H.1525 . Budapest . Hungary . b'~uthotro whom correspondence should be addressed. 01996 by the U.S. Secretary of Commerce on behalf of the United States . All rizhts reserved . This copyright is assigned to the American Institute of Physics and the American Chemical Society . Reprints available from ACS; see Reprints List at back of issue . List of Tables 1. Solvents and CAS registry numbers . . . . . . . .6 39 2 . Theta-temperatures of PS solutions . . . . . . . . 6. 4 3 Footnotes employed in Tables 3 12 . . . . . . . .6 16 3. PS in methyl acetate. . . . . . . . . . . . . . . . . . . .6.4 6 4 . PS in ethyl acetate . . . . . . . . . . . . . . . . . . . . .6.4 6 5 . PS in n-propyl acetate . . . . . . . . . . . . . . . . . . . 646 6 . PS in i-propyl acetate . . . . . . . . . . . . . . . . . . .6.4 6 7 . PS in n-butyl acetate . . . . . . . . . . . . . . . . . . . . 646 8. PS in i-butyl acetate . . . . . . . . . . . . . . . . . . . .6.4 6 9 . PS in t-butyl acetate . . . . . . . . . . . . . . . . . . . .6.4 7 10. PS in n-pentyl acetate . . . . . . . . . . . . . . . . . .6.4 7 11 . PS in n-hexyl acetate . . . . . . . . . . . . . . . . . . . . 647 12. PS in i-amyl acetate . . . . . . . . . . . . . . . . . . . .6.4 7 13. PS in cyclohexanol . . . . . . . . . . . . . . . . . . . . .6.4 7 14 . PS in n-hexane . . . . . . . . . . . . . . . . . . . . . . . . . 647 15. PS in n-heptane . . . . . . . . . . . . . . . . . . . . . . .6.4 7 16 . PS in n-octane . . . . . . . . . . . . . . . . . . . . . . . . . 647 17 . PS in cyclopenfane . . . . . . . . . . . . . . . . . . . . . . 647 18. PS in cyclohexane . . . . . . . . . . . . . . . . . . . . .6.4 8 13. PS in dcutcrntcd cyclohcxanc . . . . . . . . . . . .6.4 9 20 . PS in cycloheptane. . . . . . . . . . . . . . . . . . . . .6.4 9 21 . PS in cyclooctane . . . . . . . . . . . . . . . . . . . . . . . 649 22 . PS in cyclodecane . . . . . . . . . . . . . . . . . . . . . . 649 23 . PS in methylcyclopentane . . . . . . . . . . . . . . . . 649 24 . PS in deuterated methylcyclopentane . . . . . . .6 49 25 . PS in methylcyclohexane . . . . . . . . . . . . . . . . .6 50 26 . PS in 1,4 dimerhylcyclohexane . . . . . . . . . . .6.5 0 27 . PS in ethylcyclohexane . . . . . . . . . . . . . . . . . . 650 28 . PS in trans-decalin . . . . . . . . . . . . . . . . . . . . . . 650 29 . PSinbenzene . . . . . . . . . . . . . . . . . . . . . . . . . 6. 5 0 30 . PS in toluene . . . . . . . . . . . . . . . . . . . . . . . . . .6 51 3 1 . PS in diethylmalonate . . . . . . . . . . . . . . . . . . . 651 32 . PS in diethyloxalate . . . . . . . . . . . . . . . . . . . . . 651 33 PS in ethyl-n-butyrate . . . . . . . . . . . . . . . . . 651 34 . PS in diethylether. . . . . . . . . . . . . . . . . . . . . . .6 51 35 . PS in dioctylphthalate . . . . . . . . . . . . . . . . . . . 651 36 . PS in ethylformate . . . . . . . . . . . . . . . . . . . . . . 651 37 . PS in acetone . . . . . . . . . . . . . . . . . . . . . . . . . . 651 0047.2689/96/25(2)/637/25/$12.00 637 J . Phys . Chem . Ref . Data, Vol . 25. No . 2. 1996